TRANSPORTATION of HAZARDOUS MATERIALS is the area that is very important due to the high potential of possible incidents, despite high safety statistics. Determining indicator and assessment of HAZARDOUS MATERIALS’ risk, is the first step t execute route direction projects and also, a way to plan and assess function of road network. Here, in this article, we suggest a method to determine the risk to transport HAZARDOUS MATERIALS from arc of a network, using questionarie date and process to hierarchy assessment. The results of this study show that routes of shiraz-Nourabad. Sepidan, kazeroun-Dashte arzan, and Qotb.abad-Fath. abad, have the most risk and route of Arsanjan-jamal.abad has the least risk to pass inflammable fluid. Also, the routes of Dashte arzan-Qaemieh, Kazeroun-Dashte arzan, and Marvdasht-Shiraz have the most risk and route of Khosvieh-Hajiabad has the least risk to pass HAZARDOUS MATERIALS.